Multiple jumps and vacancy diffusion in a face-centered cubic metal

The diffusion of monovacancies in gold has been studied by computer simulation. Multiple jumps have been found to play a central role in the atomic dynamics at high temperature, and have been shown to be responsible for an upward curvature in the Arrhenius plot of the diffusion coefficient. Appropriate saddle points on the potential energy surface have been found, supporting the interpretation of vacancy multiple jumps as distinct migration mechanisms.Comment: 16 page

Crossover between hydrodynamic and kinetic modes in binary liquid alloys

Inelastic x-ray scattering (IXS) measurements of the dynamic structure factor in liquid Na57K43, sensitive to the atomic-scale coarse graining, reveal a sound velocity value exceeding the long wavelength, continuum value and indicate the coexistence of two phonon-like modes. Applying Generalized Collective Mode (GCM) analysis scheme, we show that the positive dispersion of the sound velocity occurs in a wavelength region below the crossover from hydrodynamic to atom-type excitations and, therefore, it can not be explained as sound propagation over the light specie (Na) network. The present result experimentally proves the existence of positive dispersion in a binary mixture due to a relaxation process, as opposed to fast sound phenomena.Comment: 7 pages, 8 figures, to appear in "Physical Review B

Role of Anisotropy and Refractive Index in Scattering and Whiteness Optimization

This is the final version. Available from Wiley via the DOI in this record.The ability to manipulate light–matter interaction to tailor the scattering properties of materials is crucial to many aspects of everyday life, from paints to lighting, and to many fundamental concepts in disordered photonics. Light transport and scattering in a granular disordered medium are dictated by the spatial distribution (structure factor) and the scattering properties (form factor and refractive index) of its building blocks. As yet, however, the importance of anisotropy in such systems has not been considered. Here, a systematic numerical survey that disentangles and quantifies the role of different kinds and degrees of anisotropy in scattering optimization is reported. It is shown that ensembles of uncorrelated, anisotropic particles with nematic ordering enables to increase by 20% the reflectance of low-refractive index media (n = 1.55), using only three-quarters of material compared to their isotropic counterpart. Additionally, these systems exhibit a whiteness comparable to conventionally used high-refractive index media, e.g., TiO2 (n = 2.60). Therefore, the findings not only provide an understanding of the role of anisotropy in scattering optimization, but they also showcase a novel strategy to replace inorganic white enhancers with sustainable and biocompatible products made of biopolymers.Biotechnology and Biological Sciences Research Council (BBSRC)European Research Council (ERC)Leverhulme Trus

Bio-inspired Highly Scattering Networks via Polymer Phase Separation

A common strategy to optimize whiteness in living organisms consists in using three-dimensional random networks with dense and polydisperse scattering elements constituted by relatively low-refractive index materials. Inspired by these natural architectures, we developed a fast and scalable method to produce highly scattering porous polymer films via phase separation. By varying the molecular weight of the polymer, we modified the morphology of the porous films and therefore tuned their scattering properties. The achieved transport mean free paths are in the micrometer range, improving the scattering strength of analogous low-refractive index systems, e.g. standard white paper, by an order of magnitude. The produced porous films show a broadband reflectivity of approximately 75 % whilst only 4 m thick. In addition, the films are flexible and can be readily index-matched with water (i.e. they become transparent when wet), allowing for various applications such as coatings with tunable transmittance and responsive paints

QueryTogether: Enabling entity-centric exploration in multi-device collaborative search

Collaborative and co-located information access is becoming increasingly common. However, fairly little attention has been devoted to the design of ubiquitous computing approaches for spontaneous exploration of large information spaces enabling co-located collaboration. We investigate whether an entity-based user interface provides a solution to support co-located search on heterogeneous devices. We present the design and implementation of QueryTogether, a multi-device collaborative search tool through which entities such as people, documents, and keywords can be used to compose queries that can be shared to a public screen or specific users with easy touch enabled interaction. We conducted mixed-methods user experiments with twenty seven participants (nine groups of three people), to compare the collaborative search with QueryTogether to a baseline adopting established search and collaboration interfaces. Results show that QueryTogether led to more balanced contribution and search engagement. While the overall s-recall in search was similar, in the QueryTogether condition participants found most of the relevant results earlier in the tasks, and for more than half of the queries avoided text entry by manipulating recommended entities. The video analysis demonstrated a more consistent common ground through increased attention to the common screen, and more transitions between collaboration styles. Therefore, this provided a better fit for the spontaneity of ubiquitous scenarios. QueryTogether and the corresponding study demonstrate the importance of entity based interfaces to improve collaboration by facilitating balanced participation, flexibility of collaboration styles and social processing of search entities across conversation and devices. The findings promote a vision of collaborative search support in spontaneous and ubiquitous multi-device settings, and better linking of conversation objects to searchable entities

Flexible entity search on surfaces

Surface computing allows flexible search interaction where users can manipulate the representation of entities recommended for them to create new queries or augment existing queries by taking advantage of increased screen estate and almost physical tactile interaction. We demonstrate a search system based on 1) Direct Manipulation of Entity Representation on Surfaces and 2) Entity Recommendation and Document Retrieval. Entities are modeled as a knowledge-graph and the relevances of entities are computed using the graph structure. Users can manipulate the representation of entities via spatial grouping and assigning preferences on entities. Our contribution can help to design effective information exploration systems that take advantage of large surfaces

A Flexible Enterprise Needs an Adaptable eBusiness Architecture in Order to Satisfy Naturally Evolving Requirements

Standards for exchange of purchasing information, such as ANSI X-12 for EDI, have been used by large industries (e.g. retail and auto) for almost 30 years. Newer web-based tools and new standards hold the promise of reduced cost and wider applicability. For many small to medium sized enterprises, the cost and rigidity of existing tools out weight the prospective gains, which must be amortised over comparatively few transactions. In this paper, we describe the development of an N-tiered, object-oriented, architecture for interacting with suppliers based on emerging web tools. We explore the ways in which the project was required to adapt to existing purchasing systems and the ways that the project evolved during its development. We identify patterns in the inevitable evolution of requirements during the implementation, and we describe the ways that the architecture facilitated the satisfaction of these changing requirements. By analysing the major “transition points” during the development, we attempt to document the fundamental nature of evolving requirements and the need to explicitly reflect them in adaptable e-business architectures

A wearable multimodal interface for exploring urban points of interest

Locating points of interest (POIs) in cities is typically facilitated by visual aids such as paper maps, brochures, and mobile applications. However, these techniques require visual attention, which ideally should be on the surroundings. Non-visual techniques for navigating towards specific POIs typically lack support for free exploration of the city or more detailed guidance. To overcome these issues, we propose a multimodal, wearable system for alerting the user of nearby recommended POIs. The system, built around a tactile glove, provides audio-tactile cues when a new POI is in the vicinity, and more detailed information and guidance if the user expresses interest in this POI. We evaluated the system in a field study, comparing it to a visual baseline application. The encouraging results show that the glovebased system helps keep the attention on the surroundings and that its performance is on the same level as that of the baseline

Hereditary Character of Photonics Structure in Pachyrhynchus sarcitis Weevils: Color Changes via One Generation Hybridization

Pachyrhynchus sarcitis weevils are flightless weevils characterized by colored patches of scales on their dark elytra. The vivid colors of such patches result from the reflection of differently oriented three-dimensional photonic crystals within their scales. Our results show that hybrid P. sarcitis, the first filial generation of two P. sarcitis populations from Lanyu Island (Taiwan) and Babuyan Island (Philippines), mixes the color of its ancestors by tuning the photonic structure in its scales. A careful spectroscopical and anatomical analysis of the weevils in the phylogeny reveals the hereditary characteristics of the photonic crystals within their scales in terms of lattice constant, orientation and domain size. Monitoring how structural coloration is inherited by offspring highlights the versatility of photonic structures to completely redesign the optical response of living organisms. Such finding shed light onto the evolution and development mechanisms of structural coloration in Pachyrhynchus weevils and provides inspiration for the design of visual appearance in artificial photonic materials.NanoBio-ICMG platform (FR 2607) Cambridge Trus

Designing for Exploratory Search on Touch Devices

Exploratory search confront users with challenges in expressing search intents as the current search interfaces require investigating result listings to identify search directions, iterative typing, and reformulating queries. We present the design of Exploration Wall, a touch-based search user interface that allows incremental exploration and sense-making of large information spaces by combining entity search, flexible use of result entities as query parameters, and spatial configuration of search streams that are visualized for interaction. Entities can be flexibly reused to modify and create new search streams, and manipulated to inspect their relationships with other entities. Data comprising of task-based experiments comparing Exploration Wall with conventional search user interface indicate that Exploration Wall achieves significantly improved recall for exploratory search tasks while preserving precision. Subjective feedback supports our design choices and indicates improved user satisfaction and engagement. Our findings can help to design user interfaces that can effectively support exploratory search on touch devices